{"id":300,"date":"2018-04-23T07:45:49","date_gmt":"2018-04-23T07:45:49","guid":{"rendered":"http:\/\/www.milq.info\/?page_id=300"},"modified":"2026-07-20T19:13:26","modified_gmt":"2026-07-20T17:13:26","slug":"m49_stetigkeitsbedingungen","status":"publish","type":"page","link":"https:\/\/www.milq.info\/en\/m49_stetigkeitsbedingungen\/","title":{"rendered":"Continuity conditions"},"content":{"rendered":"<div id=\"bsf_rt_marker\"><\/div><p><\/p>\n<p>The Schr\u00f6dinger equation requires calculating the second derivative of the wave function with respect to position. Therefore, at the very least the wave function and its first derivative must be continuous.<\/p>\n<p>1. Wave function continuous at <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.milq.info\/wp-content\/ql-cache\/quicklatex.com-ae48304910b3a844f49cf65f2463462e_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#120;&#32;&#61;&#32;&#92;&#100;&#102;&#114;&#97;&#99;&#123;&#97;&#125;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"34\" width=\"48\" style=\"vertical-align: -13px;\"\/>:<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.milq.info\/wp-content\/ql-cache\/quicklatex.com-5312157c9db4e50f167bd5546790c4b2_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#66;&#32;&#92;&#99;&#111;&#115;&#92;&#98;&#105;&#103;&#103;&#108;&#40;&#92;&#100;&#102;&#114;&#97;&#99;&#123;&#107;&#97;&#125;&#123;&#50;&#125;&#92;&#98;&#105;&#103;&#103;&#114;&#41;&#32;&#61;&#32;&#67;&#32;&#92;&#116;&#101;&#120;&#116;&#123;&#101;&#120;&#112;&#125;&#92;&#98;&#105;&#103;&#103;&#108;&#40;&#45;&#92;&#100;&#102;&#114;&#97;&#99;&#123;&#103;&#97;&#125;&#123;&#50;&#125;&#92;&#98;&#105;&#103;&#103;&#114;&#41;&#32;&#92;&#113;&#117;&#97;&#100;&#32;&#92;&#116;&#101;&#120;&#116;&#123;&#40;&#49;&#41;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"45\" width=\"271\" style=\"vertical-align: -18px;\"\/><\/p>\n<p>2. Derivative of the wave function at <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.milq.info\/wp-content\/ql-cache\/quicklatex.com-ae48304910b3a844f49cf65f2463462e_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#120;&#32;&#61;&#32;&#92;&#100;&#102;&#114;&#97;&#99;&#123;&#97;&#125;&#123;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"34\" width=\"48\" style=\"vertical-align: -13px;\"\/>:<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.milq.info\/wp-content\/ql-cache\/quicklatex.com-e4890a21dc75e8cdd1ed58a8b9b0acc8_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#45;&#32;&#66;&#32;&#107;&#32;&#92;&#115;&#105;&#110;&#92;&#98;&#105;&#103;&#103;&#108;&#40;&#92;&#100;&#102;&#114;&#97;&#99;&#123;&#107;&#97;&#125;&#123;&#50;&#125;&#92;&#98;&#105;&#103;&#103;&#114;&#41;&#32;&#61;&#32;&#45;&#32;&#67;&#32;&#103;&#32;&#92;&#116;&#101;&#120;&#116;&#123;&#101;&#120;&#112;&#125;&#92;&#98;&#105;&#103;&#103;&#108;&#40;&#45;&#92;&#100;&#102;&#114;&#97;&#99;&#123;&#103;&#97;&#125;&#123;&#50;&#125;&#92;&#98;&#105;&#103;&#103;&#114;&#41;&#32;&#92;&#113;&#117;&#97;&#100;&#32;&#92;&#116;&#101;&#120;&#116;&#123;&#40;&#50;&#41;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"45\" width=\"317\" style=\"vertical-align: -18px;\"\/><\/p>\n<p>Substituting the two equations into one another gives:<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.milq.info\/wp-content\/ql-cache\/quicklatex.com-c389ce7debd6a1967c4ce9e270893bd3_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#45;&#32;&#66;&#32;&#107;&#32;&#92;&#115;&#105;&#110;&#92;&#98;&#105;&#103;&#103;&#108;&#40;&#92;&#100;&#102;&#114;&#97;&#99;&#123;&#107;&#97;&#125;&#123;&#50;&#125;&#92;&#98;&#105;&#103;&#103;&#114;&#41;&#32;&#61;&#32;&#45;&#32;&#103;&#32;&#66;&#32;&#92;&#99;&#111;&#115;&#92;&#98;&#105;&#103;&#103;&#108;&#40;&#92;&#100;&#102;&#114;&#97;&#99;&#123;&#107;&#97;&#125;&#123;&#50;&#125;&#92;&#98;&#105;&#103;&#103;&#114;&#41;&#32;&#92;&#113;&#117;&#97;&#100;&#32;&#92;&#116;&#101;&#120;&#116;&#123;&#111;&#114;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"45\" width=\"297\" style=\"vertical-align: -18px;\"\/><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.milq.info\/wp-content\/ql-cache\/quicklatex.com-3d50790b58005dc1607ab1be48a2ae65_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#107;&#32;&#92;&#99;&#100;&#111;&#116;&#32;&#92;&#116;&#97;&#110;&#92;&#98;&#105;&#103;&#103;&#108;&#40;&#92;&#100;&#102;&#114;&#97;&#99;&#123;&#107;&#97;&#125;&#123;&#50;&#125;&#92;&#98;&#105;&#103;&#103;&#114;&#41;&#32;&#61;&#32;&#92;&#103;&#97;&#109;&#109;&#97;&#32;&#61;&#32;&#92;&#115;&#113;&#114;&#116;&#123;&#92;&#100;&#102;&#114;&#97;&#99;&#123;&#50;&#109;&#86;&#95;&#48;&#125;&#123;&#92;&#104;&#98;&#97;&#114;&#94;&#50;&#125;&#32;&#45;&#32;&#107;&#94;&#50;&#125;\" title=\"Rendered by QuickLaTeX.com\" height=\"48\" width=\"273\" style=\"vertical-align: -18px;\"\/><\/p>\n<p>This condition must be satisfied for a solution of the homogeneous system of equations (1), (2) to exist. The last equation is a transcendental equation for determining the possible values of <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.milq.info\/wp-content\/ql-cache\/quicklatex.com-61ba85b1984abe31fd192cc46aff8293_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#107;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"9\" style=\"vertical-align: 0px;\"\/>, and hence the possible values of the energy <img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/www.milq.info\/wp-content\/ql-cache\/quicklatex.com-c4c95473d51099f41ada4e7bf3a69076_l3.png\" class=\"ql-img-inline-formula quicklatex-auto-format\" alt=\"&#69;\" title=\"Rendered by QuickLaTeX.com\" height=\"13\" width=\"15\" style=\"vertical-align: 0px;\"\/>, which, as is well known, cannot generally be solved in closed form.<\/p>\n<p><a href=\"https:\/\/www.milq.info\/en\/mehr\/10-potentiale\/\">Back<\/a><\/p>\n<p><\/p>","protected":false},"excerpt":{"rendered":"<p>The Schr\u00f6dinger equation requires calculating the second derivative of the wave function with respect to position. Therefore, at the very least the wave function and its first derivative must be continuous. 1. Wave function continuous at : 2. Derivative of the wave function at : Substituting the two equations into one another gives: This condition&hellip; <a href=\"https:\/\/www.milq.info\/en\/m49_stetigkeitsbedingungen\/\" class=\"more-link\">Continue reading <span class=\"screen-reader-text\">Continuity conditions<\/span><\/a><\/p>\n","protected":false},"author":5,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-300","page","type-page","status-publish","hentry","without-featured-image"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v28.3 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Continuity conditions - milq<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.milq.info\/en\/m49_stetigkeitsbedingungen\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Continuity conditions - milq\" \/>\n<meta property=\"og:description\" content=\"The Schr\u00f6dinger equation requires calculating the second derivative of the wave function with respect to position. 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